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Persistent ROS generation or electrophilic stress can oxidize GSH to GSSG more rapidly than it is reduced, thereby depleting the reduced thiol pool

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This in turn weakens the skin barrier and applying ceramides topically has been shown to replenish what's been lost to restore barrier function

doi: 10.1038/s41598-017-13141-5 164 DadaraAABhardwajRAliYBMSkellyPJ