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Activation paradigms for 1,2-dithiolane-based molecules (e.g., TRFS-green) involve a TrxR-initiated cascade reaction sequence comprising disulfide reduction, intramolecular cyclization, and cargo release (Fig

The paramagnetic nitroxides (spin-adducts) formed as a result of reactions between STs and radical species are relatively stable compounds whose EPR spectra represent structural fingerprints of the parent radical species

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