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This might indicate that GS - , which is displaced upon intramolecular disulfide formation, stays associated with the scaffold site kinetically facilitating the back reaction towards the glutathionylated state

Liu Z, Ren Z, Zhang J, Chuang CC, Kandaswamy E, Zhou T, et al

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GLP-1 receptor agonists: Beyond their pancreatic effects

GSTP1-1-mediated S-glutathionylation of PDI results in impaired isomerase activity and is potentially an upstream signaling event in UPR that could influence the functionality of other client proteins with enormous impact on cellular proteostasis [52]